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Beilstein J. Org. Chem. 2008, 4, No. 32, doi:10.3762/bjoc.4.32
Graphical Abstract
Scheme 1: Transmission of asymmetry in the conjugate addition of allyl sulfones to ethyl crotonate depending ...
Scheme 2: Preparation of donor precursors for conjugate addition (1), bearing a remote stereogenic center.
Scheme 3: Borch reductive amination of acetophenones.
Scheme 4: Preparation of [(9-anthryl)alkyl]- and (mesitylalkyl)amines 6h and 6j from nitriles via imines 8.
Figure 1: Calculated minimum energy conformation of lithiated amino-substituted sulfone 1a showing π-interact...